Design of a fuel cell system design of a specification of requirements for a fuel cell system for the electric power generation in a 77foot sailing ship master of science thesis. The fundamentals of fuel cells, how they work, their history, and much more. Types of fuel cell and their classification are given and desired properties of the polymeric membranes for use in pemfc are described. Renewable resourcessuch as solar, wind, and biomassare just some of the domestic resources available for.
Box 880 morgantown, west virginia 265070880 november 2004. This paper will be very helpful for undergraduate researches, history and. A fuel cell is an electrochemical device that converts the chemical energy of a fuel directly into electrical energy. Although analytical solutions in buttlervolmer form can be found if a single ratedetermining. A fuel cell is an electrochemical cell that converts the chemical energy of a fuel often hydrogen and an oxidizing agent often oxygen into electricity through a pair of redox reactions.
Fuel cells fundamentals and applications request pdf. The performance of a fuel cell device can be summarized with a graph of its current. Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side with. Fuel cells fundamentals and applications fuel cells fundamentals and applications carrette, l friedrich, k. Prinz solution companion to fuel cell fundamentals. It also defines how reversible fuel cell voltages are affected by departures from the standard state. In areas where availability or delivery of industrial hydrogen is limited. Focusing on the fundamentals, it provides straightforward descriptions of how fuel cells work, why they offer the potential for high efficiency, and how their unique advantages can best be used. Volume 1, fundamentals and survey of systems, provides the necessary background information on fuel cells, including the fundamental principles such as the thermodyamics and kinetics of fuel cell reactions, mass and heat transfer in fuel cells, and an overview of the key principles of the most important types of fuel cell, and their related. A fuel cell is an electrochemical cell that converts the chemical energy of a fuel often. Fuel cells are considered environment benign technology providing solutions to a range of environmental.
An introduction to fuel cells and hydrogen technology by brian cook, heliocentris vancouver, canada whereas the 19th century was the century of the steam engine and the 20th century was the century of the internal combustion engine, it is likely that the 21st century will be the century of the fuel cell. By using fitting tools, correlations are proposed with. A fuel cell is an electrochemical device that continuously and directly converts the chemical energy of externally supplied fuel and oxidant to electrical energy. Progress and accomplishments in hydrogen and fuel cells pdf. Download solution manual fuel cell fundamentals 2nd ed. An introduction to fuel cell technology and economics. Fuel cell fundamentals textbook solutions from chegg, view all supported editions. Fuel cell fundamentalssolutions mae 628 fuel cells studocu. In this chapter fuel cell introduction and general concepts about fuel cell are presented. Objectives explain the operation of the various carburetor systems compare fuel injection to carburetion identify the different types of fuel injection describe the design and function of electronic fuel injection components understand how a computer feedback system works.
The stack voltage is calculated as a function of stack current, cell temperature, air pressure, oxygen and hydrogen partial pressures, and membrane humidity. Fuel cell fundamentals provides a thorough introduction to the principles and practicaliti. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen usually from air to sustain the chemical reaction, whereas in a battery the chemical energy usually. The current produced by a fuel cell scales with the size of the reaction area where the reactants, the electrode, and the electrolyte meet. At the end challenges facing the fuel cell industry and their future outlook are briefly discussed. Supramaniam srinivasan 19322004 obtained his bachelor of science with honors in chemistry from the university of ceylon in l955 and his phd in physical chemistry from the university of pennsylvania in 1963. Characterization and modeling are pivotal to the development and advancement of fuel cell. Holme ryan ohayre suk won cha whitney colella fritz b. Prinz table of contents nomenclature i fuel cell principles 1 introduction 3 2 fuel cell thermodynamics 25 3 fuel cell reaction kinetics 71 4 fuel cell charge transport 111 5 fuel cell mass transport 161.
The fuel cell stack model in chapter 3 is composed of four interacting submodels, namely, stack voltage, cathode. Find 97811191805 fuel cell fundamentals 3rd edition by prinz et al at over 30 bookstores. Fuel cell fundamentals provides a thorough introduction to the principles and practicalities behind fuel cell technology. G o of the overall reaction of the fuel cell is given by. Suggested grading schemes are given after the problem numbers. One is that fossil fuels are limited in amount, and the other are the environmental problems that are emerging due to their use.
First fuel cellfirst fuel cell 3 in 1839, william grove, a british jurist and amateur physicist, first discovered the principle of the fuel cell. High temperature solid oxide fuel cellsfundamentals, design and applications. The chapter examines how temperature and pressure affect the maximum electrical work available from the fuel cell. Just like in other batteries the chemical process is divided up into the. Further, the paper looks to introduce both the technical and economic issues facing the introduction of this technology. Fuel cells fundamentals and applications, fuel cells. Grove utilized four cells, each containing hydrogen and oxygen, to produce electric power which was then used to split the water in the smaller upper cell into hydrogen and oxygen. Fundamentals many companies and research groups work on developing different types of pfc technologies to make them more advantageous than their competing technologies, i. Additionally, the paper presents the basic concepts, applications for the six main types of fuel cell technologies. The title of his phd is mechanism of electrolyte hydrogen evolution. The real efficiency of a fuel cell must always be less than reversible thermodynamic efficiency. In chapter 12, different fuel cell systems are described, mainly focusing on their operation principles and characteristics, technologies, and fuel supplies. Finally, it is intended with the paper to present the concepts and history related to the fuel cells in a basic way.
Carrette and others published fuel cells fundamentals and applications find, read and cite all the research you need on researchgate. Fuel cells for education university of tennessee at. The major types of fuel cells, including proton exchange mem. However, battery manufacturers always seek solutions to increase the battery energy densities. Fundamentals and applications wiley online library. Isbn 97811191805 fuel cell fundamentals 3rd edition. Economics of fuel cell solutions for material handling. Hydrogen and fuel cell basics hydrogen and fuel cells nrel. Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side with guidance on system. Department of energy office of fossil energy national energy technology laboratory p. The second cell has an asr0 a0 r0 10a r9, or an asr 10 9 higher than the first cell, so the losses 10 increase by a factor of 9 over the first cell. In chapter, the systematic design of fuel cell hybrid drive trains is introduced. The cell will run out of copper sulfate much before it runs out of zinc. Fuel cell fundamentalssolutions mae 628 fuel cells.
Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side. The onestep from chemical to electrical energy nature of this process, in comparison to the multistep e. Fuel cell systems are explained and analyzed, including single cells and stacks, and balanceofplant fundamentals, with emphasis upon prevalent fuel cell types and their applications. It is well known that the use of fossil fuels to produce energy leads to two major problems. Hydrogen fuel cell technology for the sustainable future of. G o nfe o,cell 1 where n is the number of electrons transferred and f is faradays constant 96,475 cequiv. A complete, uptodate, introductory guide to fuel cell technology and application. Request pdf on jan 1, 2009, sukwon cha and others published fuel cell fundamentals find, read and cite all the research you need on researchgate.
Discuss at least two potential applications where the unique attributes of fuel cells make them attractive. Fuel cell systems are a clean, efficient, reliable, and quiet source of power. Fuel cell fundamentals is an introductorylevel textbook covering the basic science and engineering behind fuel cell technology. An isotope effect study, which he did under the direction of professor john omara. The space between the two electrodes is filled with a concentrated solution of. Fuel cell fundamentafuel cell fundamentalssolutionsls. View homework help fuel cell fundamentalssolutions. Fuel cell electric vehicles fcevs fueled by hydrogen are poised to play an important role in our nations portfolio of sustainable transportation options. Supplementary solutions 57 a in the leadacid battery, each mole of pbs transfers 2 mol of eto each mol of pbo2 to make pbso4. E cell e rev i r electronic r membrane hor orr i r h eff tx gasdry wet 1 1 where e rev. James larminie and andrew dicks, fuel cell systems explained, 2nd edition, john wiley and sons, 2003. A fuel cell test system 850e, hydrogen, oxygen and nitrogen tanks, and a pefc single cell were employed to conduct experimental work. Vehicular applications of fuel cells are also explained. List three major advantages and three major disadvantages of fuel cells compared to other power conversion devices.